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Titanium(IV) chloride 四氯化钛

规格: 99% (99.9999%-Ti)

CAS: 7550-45-0

产品编号: H64688

MDL: MFCD00011267

品牌: INFI

Chemical Name	Titanium(IV) chloride
Synonym	(t-4)-titaniumchloride(ticl4 TITANIUM ATOMIC SPECTROSCOPY STANDARD (TICL4) TITANIUM CHLORIDE TITANIUM(IV) CHLORIDE TITANIUM(IV) TETRACHLORIDE Tetrachlorotitanium Tetrachlorotitanium; Titanic chloride Tetrachlorure de titane Titane Titanic chloride Titanium chloride (TiCl4) (t-4)- Titanium tetrachl Titanium tetrachloride Titanium tetrachloride, Titanic chloride Titanium tetrachloride; Titanic chloride Titantetrachlorid tetrachloruredetitane titane(tetrachlorurede)(french) 四氯化钛四氯化钛(IV) 四氯化钛(IV) 溶液四氯化钛四氯化钛(IV), 99.0% MIN, TYPICALLY 99.6% 四氯化钛(禁运) 四氯化钛, 99.99% (METALS BASIS) 氯化钛氯化钛;TTC
CAS Number	7550-45-0
EC Number	231-441-9
MDL Number
Merck Number	9478
PubChem Substance ID	87558543
Beilstein Registry Number	2384789
Chemical Name Translation	四氯化钛(IV)
InChIKey	XJDNKRIXUMDJCW-UHFFFAOYSA-J
Wiswesser Line Notation	TI G4
LabNetwork Molecule ID	LN00220931
IUPAC Name	tetrachlorotitanium

活化四氢吡咯以提高通过修正的波沃反应转化成相应的 α,α-二甲胺的转化率。促进 (S)-2-苄氧-3-戊酮在 THF 或 DME 中的高选择性羟醛缩合反应。

{ALFA} Conversion of ketones to N-alkylimines: Org. Synth. Coll., 6, 818 (1988); Acta Chem. Scand., 46, 1211 (1992). Aldol condensation of aryl ketones with aryl aldehydes: Tetrahedron Lett., 28, 4135 (1987). Crossed aldol condensation of silyl enol ethers with carbonyl compounds: J. Am. Chem. Soc., 96, 7503 (1974); Org. Synth. Coll., 8, 323 (1993). ɑ-Tert-alkylation of ketones by reaction of the silyl enol ether with a tertiary halide: Org. Synth. Coll., 7, 424 (1990); review: Angew. Chem. Int. Ed., 21, 96 (1982); see also Zinc chloride, A16281. Michael addition of silyl enol ethers to ɑß-enones: Org. Synth. Coll., 8, 210 (1993). For conjugate allylation of ɑß-enones, see Allyltrimethylsilane, A14662. Regiospecific [3+2] annulation of enones with silylated allenes: J. Am. Chem. Soc., 103, 1604 (1981); Tetrahedron, 39, 935 (1983); Org. Synth. Coll., 8, 347 (1993):

{ALFA} Examples of reactions mediated by TiCl4:

{ALFA} For use in a diastereoselective Mannich reaction, see: Helv. Chim. Acta, 67, 1593 (1984). Also used in combination with reducing agents for the generation of low-valent Ti species, which effect the reduction of various functional groups:

{PUB} Hazardous Substances Data Bank (HSDB)|PubChem --- Abnormalities of pulmonary function and pleural disease among titanium metal production workers. --- https://pubmed.ncbi.nlm.nih.gov/3495034

{ALFA} In combination with NaI, for reduction o

{ALF} In combination with NaI, for reduction of amine oxides and nitrones to amines: Chem. Ber., 123, 647 (1990); and sulfoxides to sulfides: Synthesis, 155 (1991). With Mg, for deoxygenation of aromatic N-oxides: Synthesis, 732 (1987). With LAH for the otherwise difficult reduction of sulfones to sulfides: J. Chem. Soc., Chem. Commun., 761 (1994). Reviews of low-valent titanium reagents in organic synthesis: Synthesis, 883 (1989); J. Organomet. Chem., 405, 1 (1991); J. Prakt. Chem./ Chem. Ztg., 337, 250 (1995).

{ALD} Merck: 14,9478

{ALFA} Modera

7550-45-0 H64688 Titanium(IV) chloride
四氯化钛

化学属性

Mol. Formula	TiCl4
Mol. Weight	190.00
Density	1.726
Boiling Point	135-136
Melting Point	-25
Refractive index	1.6059
Solubility	Soluble in dilute hydrochloric acid, alcohol and alkalies.
TSCA	Yes
Flash Point	8°(46°F)
Vapor Pressure	24.09 psi ( 55 °C)
Stability	对湿度敏感
Appearance	pale yellow liq.
Danger-Level	甲类
pH	-:A
Redox	-

*以上化合物性质及应用等信息仅供参考

电子化学品

催化剂

配体

有机硅

元素分类

其他精细新材料

Titanium(IV) chloride 四氯化钛

规格: 99% (99.9999%-Ti)

化学属性

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