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Ferric acetylacetonate 三乙酰丙酮铁

规格: 98%
CAS: 14024-18-1
产品编号: H63835
MDL: MFCD00000020
品牌: INFI
Chemical NameIron(III) Acetylacetonate
CAS Number14024-18-1
EC Number237-853-5
Beilstein Registry Number4157960
MDL NumberMFCD00000020
PubChem Substance ID87571482
Synonym (Acetylacetonato)iron(III) (OC-6-11)-tris(2,4-pent (OC-6-11)-tris(2,4-pentane dionato-O,o')-iron 2,4-Eisen(III)-acetylacetonat 2,4-Pentanedione, iron(III) derivative 2,4-Pentanedione; Ferric acetylacetonate; Ferric acetylacetonate; 2,4-Pentanedione, iron(III) derivative 2,4-戊二酸铁(III) 4-戊二酮-O Acetope Fe(II) Fe(acac)3 Ferric acetylacetonate Ferric tris(acetylacetonate) Iron (III) 2,4-pentanedionate Iron acetylacetonate Iron acetylacetone Iron tris(2,4-pentanedionato) Iron tris(acetoacetonate) Iron tris(acetylacetonate) Iron(3+) acetylacetonate Iron(III) acetylacetonateTris(acetylacetonato)iron(III) Iron, tris(2,4-pentane Tris(acetylacetonato)-eisen(III) Tris(acetylacetonato)iron
Chemical Name Translation乙酰丙酮铁(III)
Wiswesser Line NotationD6O-FE-O BDJ D1 F1 B-& BD6O-FE-O BDJ D1 F1 B-&BD6O-FE-O BDJ D1 F1
  • 用作树脂交联剂合固化促进基;橡胶添加剂;石油裂解催化剂;燃料油添加剂,可改善润滑性和燃烧性;有机合成催化剂。
  • {ALF} In combination with Na metal at room temperature in benzene, cyano groups are cleaved from alkyl nitriles to give the corresponding hydrocarbons: J. Am. Chem. Soc., 93, 7113 (1971).
  • {uni_hamburg} Short: III/5b
  • {ALF} Catalyzes the nitration of non-activated arenes, e.g. halogenobenzenes, and moderately activated arenes, e.g. alkylbenzenes and naphthalenes under non-acidic, non-aqueous conditions with NO2 in the presence of O2; no nitration occurs in the absence of the Fe(III) catalyst: J. Chem. Soc., Perkin 1, 2385 (1996).
  • {ALF} Catalyst for the coupling of Grignard reagents with aryl halides: J. Am. Chem. Soc., 124, 13856 (2002); Org. Lett., 6, 1227 (2004), with vinyl sulfones to give alkenes: Tetrahedron Lett., 23, 2469 (1982); Tetrahedron, 44, 111 (1988), and with acyl halides to give ketones in good yield: Tetrahedron Lett., 25, 4805 (1984). Alkenyl halides couple with aryl Grignards to give 1-aryl alkenes: Synlett, 1901 (2001). For leading references and improved reaction conditions for the coupling of alkyl and aryl Grignards with a varirtety of enol triflates and acid chlorides, and also for selective monoalkylation of dichlroarenes and heteroarenes, see: J. Org. Chem., 69, 3743 (2004).
  • {ALD} Beilstein: 1,IV,3675
  • 14024-18-1 H63835 Ferric acetylacetonate
三乙酰丙酮铁

    化学属性

    Mol. FormulaC15H21FeO6
    Mol. Weight353
    Density5.22
    Melting Point180 - 182 °C (dec.)(lit.)
    TSCAYes
    Solubility2 G/L (20 ºC)
    Stability易吸潮
    Boiling Point110°C 2mm

    *以上化合物性质及应用等信息仅供参考