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Bismuth chloride 氯化铋

规格: 98%
CAS: 7787-60-2
产品编号: H63141
MDL: MFCD00003461
品牌: INFI
Chemical NameBismuth Trichloride
Synonym Bismuth chloride
CAS Number7787-60-2
PubChem Substance ID87561573
EC Number232-123-2
MDL NumberMFCD00003461
Merck Number1262
Beilstein Registry Number2384789
Chemical Name Translation氯化铋
Reaxys-RN3903092
LabNetwork Molecule IDLN00196712
Canonical SMILESCl[Bi](Cl)Cl
IUPAC Nametrichlorobismuthane
  • 制造铋盐,有机反应催化剂,高纯材料。
  • {ALFA} Arenes undergo sufonylation by heating with arenesulfonyl chlorides in the presence of BiCl3 (5 mol%) and triflic acid (10 mol%) to give high yields of mixed diaryl sulfones; neither BiCl3 nor TfOH alone is effective: Tetrahedron Lett., 40, 9233 (1999).
  • {ALFA} Catalyzes the addition of 1,3-dicarbonyl compounds to Michael acceptors under solvent-free conditions with microwave irradiation: Tetrahedron Lett., 38, 1449 (1997).
  • {ALFA} For a brief feature on Bi(III) catalysts, see: Synlett, 1194 (2001). For a review of their use in acylation and sulfonylation reactions, see: Synlett, 181 (2002).
  • {ALFA} For catalysis of Diels-Alder and hetero Diels-Alder reactions, see: J. Org. Chem., 62, 4880 (1997); Tetrahedron Lett., 39, 1161 (1998).
  • {PUB} Human Metabolome Database (HMDB)|PubChem|Springer Nature --- Hydrogen sulfide and colonic epithelial metabolism: implications for ulcerative colitis --- https://pubmed.ncbi.nlm.nih.gov/11508674
  • {ALFA} Lewis acid catalyst which promotes the rearrangement of acetanilides to o-amino ketones: Tetrahedron Lett., 3217 (1976).
  • {ALD} Merck: 14,1262
  • {ALFA} Promotes the chemoselective deprotection of N-Boc amino acids and peptides: Tetrahedron Lett., 47, 389 (2006).
  • {PUB} PubCh
  • {PUB} PubChem|Springer Nature --- A bioluminescent arsenite biosensor designed for inline water analyzer --- https://pubmed.ncbi.nlm.nih.gov/26769474
  • {PUB} PubChem|Springer Nature --- A molecular imprinted polymer with recognition properties towards the carcinogenic mycotoxin ochratoxin A --- https://pubmed.ncbi.nlm.nih.gov/12549882
  • {PUB} PubChem|Springer Nature --- A specific identification platform based on biscuit-like bismuth nanosheets for label-free electrochemical immunosensor --- https://pubmed.ncbi.nlm.nih.gov/35286646
  • {PUB} PubChem|Springer Nature --- Bismuth Subsalicylate Increases Intracellular Ca2+, MAP-Kinase Activity, and Cell Proliferation in Normal Human Gastric Mucous Epithelial Cells --- https://pubmed.ncbi.nlm.nih.gov/15139483
  • {PUB
  • 7787-60-2 H63141 Bismuth  chloride
氯化铋

    化学属性

    Mol. FormulaBiCl3
    Mol. Weight315.34
    Boiling Point447 ºC
    Melting Point230 - 232 ºC
    Density4.73
    TSCAYes
    SolubilitySoluble in HCl, HNO3, acetone, ethyl acetate. Insoluble in alcohol. Decomposed by water to BiOCl
    Flash Point430°C
    Appearance white xtl.
    Stabilitymoisture sensitive

    *以上化合物性质及应用等信息仅供参考