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1,3-Bis(diphenylphosphino)propane 1,3-双(二苯膦基)丙烷

规格: 95%
CAS: 6737-42-4
产品编号: H60908
MDL: MFCD00003050
品牌: INFI
Chemical Name1,3-Bis(diphenylphosphino)propane
Alfabeta NameBISDIPHENYLPHOSPHINOPROPANE 13()-,
EC Number229-791-2
Beilstein Registry Number2821785
Synonym 1,3-Bis(diphenylphosphino)propane {LY} 1,3-Bis(diphenylphosphino)propane {} {LY} 1,3-Bis(diphenylphosphino)propane {} {} {LY} 1,3-Bis(diphenylphosphino)propane {} {} {} {LY} 1,3-Bis(diphenylphosphino)propane {} {} {} {} {LY} 1,3-Bis(diphenylphosphino)propane {} {} {} {} {} {LY} 1,3-Bis(diphenylphosphino)propane {} {} {} {} {} {} {LY} 1,3-Bis(diphenylphosphino)propane {} {} {} {} {} {} {} {LY} 1,3-Bis(diphenylphosphino)propane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,3-Bis(diphenylphosphino)propane {} {} {} {} {} {} {} {} {} {LY} 1,3-Bis(diphenylphosphino)propane {} {} {} {} {} {} {} {} {} {} {LY} 1,3-Bis(diphenylphosphino)propane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,3-Bis(diphenylphosphino)propane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,3-Bis(diphenylphosphino)propane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,3-Bis(diphenylphosphino)propane {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID81219
Reaxys-RN2821785
Chemical Name Translation1,3-双(二苯基膦)丙烷
LabNetwork Molecule IDLN00155114
InChIInChI=1S/C27H26P2/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27/h1-12,14-21H,13,22-23H2
MDL NumberMFCD00003050
CAS Number6737-42-4
Canonical SMILESP(CCCP(C1=CC=CC=C1)C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4
GHS Symbol
Warnings IRRITANT
Signal word
WGK Germany3
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S37 Wear suitable gloves 戴适当手套；
    Risk Statements
    • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
      Precautionary statements
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
      • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
      • P302+P352+P332+P313+P362+P364
      • P305+P351+P338+P337+P313
        Hazard statements
        • H315 Causes skin irritation 会刺激皮肤
        • H319 Causes serious eye irritation 严重刺激眼睛
        • H335 May cause respiratory irritation 可能导致呼吸道刺激
          Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
          Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Air Sensitive {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from lig
          Hazard Codes Xi
        • {ALF} Chelating phosphorus ligand which forms a 1:1 complex with NiCl2, which is an efficient catalyst for the coupling of Grignard reagents with aryl, vinylic or heterocyclic halides: Bull. Chem. Soc. Jpn., 49, 1958 (1976); Tetrahedron, 38, 3347 (1982); Synthesis, 386 (1988).
        • {ALF} Successful Suzuki coupling of arylboronic acids with aryl chlorides bearing electron-withdrawing groups was achieved in the presence of Palladium(II)­ acetate, 10516, and dppp: Tetrahedron Lett., 38, 5575 (1997).
          • 6737-42-4 H60908 1,3-Bis(diphenylphosphino)propane 1,3-双(二苯膦基)丙烷

          化学属性

          Density1.422
          TSCAYes
          Solubility不溶
          Flash Point235°C
          Mol. FormulaC27H26P2
          Mol. Weight412.44
          Appearance white xtl.
          Melting Point63-65°C
          Boiling Point529.7°C at 760 mmHg
          RedoxReduction

          *以上化合物性质及应用等信息仅供参考

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