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Triisobutylaluminum 三异丁基铝

规格: 1.0 M solution in hexanes, SpcSeal

CAS: 100-99-2

产品编号: H59239

MDL: MFCD00008929

品牌: INFI

Chemical Name	Triisobutylaluminium
EC Number	202-906-3
Beilstein Registry Number	3587328
Synonym	ALUMINUM TRIISOBUTYL Aluminium triisobutyl Aluminiumtriisobutyl Aluminiumtris-(2-methylpropanid) Aluminum, tris(2-methylpropyl)- TIBA TIBA 三(2-甲基丙基)铝 TIBAL TIBAL cpd TRIISOBUTYLALUMINIUM TRIISOBUTYLALUMINUM Tri(isobutyl)aluminum Tri-i-butylaluminum Tri-iso-butylaluminum Triisobutylalane Triisobutylaluminummincolorlessliq Tris(2-methylpropyl)aluminium Tris(2-methylpropyl)aluminum Tris(isobutyl)aluminum triisobutyl alane triisobutyl-aluminu triisobutylalane triisobutylaluminum tris(2-methylpropyl)-Aluminum tris(isobutyl)aluminum 三异丁基铝三异丁基铝, 25% W/W IN HEXANE 三異丁基鋁
PubChem Substance ID	16682931
Chemical Name Translation	三异丁基铝
Merck Number	326
LabNetwork Molecule ID	LN00162753
InChI	InChI=1S/3C4H9.Al/c31-4(2)3;/h34H,1H2,2-3H3;
MDL Number	MFCD00008929
CAS Number	100-99-2

GHS Symbol

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 4 gm/kg
TOXIC EFFECTS :
   Gastrointestinal - other changes
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0555398

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 8000 ppm/1H
TOXIC EFFECTS :
   Sense Organs and Special Senses (Olfaction) - effect, not otherwise
   specified
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0555398

Signal word
WGK Germany	3
Safety Statements
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见； S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）； S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾； S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染； S30 Never add water to this product 切勿将水加入该产品中； S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水” S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置； S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟； S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护； S9 Keep container in a well-ventilated place 保持容器在通风良好的场所； S8 Keep container dry 保持容器干燥；
Risk Statements
R11 Highly flammable 非常易燃 R48/20 R14 Reacts violently with water 遇水会猛烈反应 R17 Spontaneously flammable in air 在空气中能够自燃 R34 Causes burns 会导致灼伤 R62 Possible risk of impaired fertility 有削弱生殖能力的危险 R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官 R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥 R51/53 R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。 P222 Do not allow contact with air. 不要与空气接触。 P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能，因为会剧烈反应可能产生闪火。 P231+P232 P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。 P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。 P301+P330+P331 P302+P334 P303+P361+P353 P304+P340 P305+P351+P338 P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。 P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。 P335+P334 P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。 P370+P378 P402+P404 P405 Store locked up. 上锁保管。 P422 Store contents under… 存储目录在…之下。 P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火 H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体，可自燃。 H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤 H318 Causes serious eye damage 严重伤害眼睛
Hazard Codes	F,C
UN Number	UN 3394 4.2/PG 1 UN3399 UN3394
Storage condition	密封保存 Air & Moisture Sensitive 充氩保存 0-6°C
Packing Group	I
Personal Protective Equipment	Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Class	4.3
RTECS	BD2203500
Warnings	危化品目录(2015)
Restrict	危险品

用于有机合成及作聚合烯烃的催化剂。

{uni_hamburg} Short: III/31a

{uni_hamburg} Short: IV/18A

{ALD} Merck:326

{uni_hamburg} Short: EINECS

{ALD} Merck:326

Beilstein:4,643

100-99-2 H59239 Triisobutylaluminum
三异丁基铝

化学属性

Refractive index	1.4494
TSCA	Yes
Flash Point	-18 ºC
Solubility	溶于苯。
Mol. Formula	C12H27Al
Mol. Weight	198.32
Density	0.781
Appearance	colorless liq.
Stability	moisture sensitive
Boiling Point	73°C/5 mm
Melting Point	4°C

*以上化合物性质及应用等信息仅供参考

电子化学品

催化剂

配体

有机硅

元素分类

其他精细新材料

Triisobutylaluminum 三异丁基铝

规格: 1.0 M solution in hexanes, SpcSeal

化学属性

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