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Phenylsilane 苯硅烷

规格: 99%, SpcSeal

CAS: 694-53-1

产品编号: H54060

MDL: MFCD00013478

品牌: INFI

有机硅系列

简介

有机硅烷类化合物主要应用在有机合成及有机硅材料领域。在有机合成中，硅烷作为羟基保护基大量存在，如三甲基氯硅烷，TBSCI,有时作为一个合成子载体存在，如乙烯基三甲基硅烷，烯丙基三甲基硅烷，六甲基二硅硫烷等，从而实现相应的官能团化反应。有机硅材料领域有硅烷偶联剂、硅油（硅脂、硅乳液、硅表面活性剂）、高温硫化硅橡胶、液体硅橡胶、硅树脂、封端剂，含硅复合共聚物等。

应用介绍及参考文献

1.如乙烯基三甲基硅烷作为一个“乙烯”合成子，用于3+2环加成反应，应用于有机合成过程中。

图片来源于期刊：Vinyltrimethylsilane, Glenn J. Fegley Gerald L. Larson, Encyclopedia of Reagents for Organic Synthesis, 2008.

2.如烯丙基三甲基硅烷，作为一个烯丙基化试剂，应用于艾日布林或者前列素类似物的合成中。

图片来源于期刊：W020050118565, WO2019102490

图片来源于期刊：Gary A. Sulikowski et al Org. Lett. 2019, 21, 10048-10051

3.作为聚合引发剂，或者烯姪共聚物，参与烯姪聚合，形成功能性有机硅材料，如耐水性硅胶粘合剂，修饰聚氟乙烯等

技术优势

产品纯度高，具有百公斤生产能力

Chemical Name	Phenylsilane
MDL Number	MFCD00013478
EC Number	211-772-5
CAS Number	694-53-1
Synonym	苯基硅烷 phenyl-silane Monophenylsilane Phenylsilane Silane, phenyl- Phenylsilane, silyl- phenylsilane Silylbenzene 苯硅烷 Phenylsilane,97% Fenylsilan Benzene, silyl- PHENYLSILANE CHLORODIMETHYL phenyl-silan
Beilstein Registry Number	2935169
PubChem Substance ID	6327628
Reaxys-RN	2935169
Chemical Name Translation	苯硅烷
InChIKey	PARWUHTVGZSQPD-UHFFFAOYSA-N
LabNetwork Molecule ID	LN00007171
InChI	InChI=1S/C6H5Si/c7-6-4-2-1-3-5-6/h1-5H

GHS Symbol

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 14500 mg/m3/2H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicenum, 1986  Volume(issue)/page/year: -,1227,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 700 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicenum, 1986  Volume(issue)/page/year: -,1227,1986

Safety Statements
S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟； S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见； S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套； S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护； S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水” S7/8 Keep container tightly closed and dry 保存在严格密闭容器中，保持干燥；
UN Number	3399
Risk Statements
R11 Highly flammable 非常易燃 R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应，释放出高度可燃气体 R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害 R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition	Moisture Sensitive Flammables area
Signal word	Danger
WGK Germany	3
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。 P231+P232 P233 Keep container tightly closed. ?保持容器密闭。 P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。 P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。 P242 Use only non-sparking tools. 只能使用无火花工具。 P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。 P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。 P264+P265 P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。 P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。 P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。 P301+P312 P301+P312+P330 P301+P317 P302+P352 P302+P352+P332+P313+P362+P364 P303+ P303+P361+P353 P304+P312 P304+P340 P305+P351+P338 P305+P351+P338+P337+P313 P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。 P317 P319 P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。 P330 Rinse mouth. 漱口 P332+P313 P332+P317 P337+P313 P337+P317 P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用 P362+P364 P370+P378 P402+P404 P403+P233 P403+P235 P405 Store locked up. 上锁保管。 P422 Store contents under… 存储目录在…之下。 P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
H225 Highly flammable liquid and vapour 高度易燃液体和蒸气 H261 In contact with water releases flammable gas 与水接触时释放可燃气体。 H302 Harmful if swallowed 吞食有害 H315 Causes skin irritation 会刺激皮肤 H319 Causes serious eye irritation 严重刺激眼睛 H332 Harmful if inhaled 吸入有害 H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment	Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECS	VV4825000
Packing Group	II
Hazard Codes	4.3 F,Xn Xn;F
Hazard Class	3

{uni_hamburg} Short: II/14a

Title: Molecular Constants: Diamagnetic Molecules

Author: Demaison, J.; Dubrulle, A.; Hüttner, W.; Tiemann, E.

Editor: Hellwege, K.-H.; Hellwege, A.M.

Source: Landolt-Börnstein, New Series

Volume: II/14a

Page: 1-788

Year: 1982

Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy

ISBN: 3-540-11365-7

ISBN: 978-3-540-11365-2

Internet Resource: DOI:10.1007/b19966

RefComment: 196 figs., XI

{uni_hamburg} Short: II/2

Title: Magnetic Properties of Coordination and Organometallic Transition Metal Compounds

Author: König, E.

Editor: Hellwege, K.-H.; Hellwege, A.M.

Source: Landolt-Börnstein, New Series

Volume: II/2

Year: 1966

ISBN: 3-540-03593-1

ISBN: 978-3-540-03593-0

Internet Resource: DOI:10.1007/b19948

RefComment: 170 figs., XII, 578 pages. Hardcover

Abstract: The data compiled refer to susceptibility measurements (susceptibility, Curie-constants, magnetic moments, transition temperatures) and ESR-measurements (g-factors and other parameters of the applied spin Hamiltonian). In volume II/2 the literature from 1899 up to 1964 has been considered. Volume II/8 supplements volume II/2, taking into account the data on magnetic susceptibilities and ESR parameters published in the p eriod 1964 to 1968. The following subvolumes II/10,II/11, II/12 supplement data up to 1974.

{uni_hamburg} Short: II/25D

Title: Structure Data of Free Polyatomic Molecules: Molecules Containing Five or More Carbon Atoms

Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N.

Editor: Kuchitsu, K.

Source: Landolt-Börnstein, New Series

Volume: II/25D

Year: 2003

Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules

ISBN: 3-540-42860-7

ISBN: 978-3-540-42860-2

Internet Resource: DOI:10.1007/b75952

RefComment: VIII, 569 pages. Hardcover

RefComment: Written for scientists and researchers in the fields of chemistry and physics

Abstract: This fourth subvolume presents data on the geometric parameters (intern

化学属性

Mol. Formula	C6H8Si
Mol. Weight	108.21
Density	0.88
Flash Point	8°C(lit.)
TSCA	Yes
Boiling Point	120
Refractive index	1.5090 to 1.5120
Melting Point	-64 to -68°C
Danger-Level	甲类

*以上化合物性质及应用等信息仅供参考

电子化学品

催化剂

配体

有机硅

元素分类

其他精细新材料

Phenylsilane 苯硅烷

规格: 99%, SpcSeal

有机硅系列

化学属性

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