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Ferrocene 二茂铁

规格: 99%
CAS: 102-54-5
产品编号: H48204
MDL: MFCD00001427
品牌: INFI
Chemical NameFerrocene
MDL NumberMFCD00001427
CAS Number102-54-5
EC Number203-039-3
Beilstein Registry Number2384789
Synonym Ferrocene
PubChem Substance ID7611
Merck Number4037
Chemical Name Translation二茂铁
Wiswesser Line NotationL50TJ 0-FE-- 0L50TJ
LabNetwork Molecule IDLN01344276
InChIInChI=1S/2C5H5.Fe/c2*1-2-4-5-3-1;/h2*1-5H;/q2*-1;+2
Canonical SMILES[][Fe][].c1cccc1.c2cccc2
  • 二茂铁是一种具有夹心结构的金属有机化合物。二茂铁及其衍生物因其本身的特点,如疏水性、生物可氧化性、芳香性、稳定性、低性、生物活性等,而被广泛应用。如作催化剂。汽油的抗爆添加剂。高温润滑剂。高温聚合物中间体。紫外光吸收剂。
  • {PUB} Crystallography Open Database (COD)|PubChem --- Electrochemical Illumination of Intramolecular Communication in Ferrocene-Containingtris-β-Diketonato Aluminum(III) Complexes; Cytotoxicity of Al(FcCOCHCOCF3)3 --- https://pubmed.ncbi.nlm.nih.gov/22272584
  • {ALF} For Mannich reaction using tetramethylmethylenediamine as the source of the Mannich intermediate, see: Org. Synth. Coll., 5, 434 (1973).
  • {ALF} In combination with TFA anhydride, reduces sulfoxides to sulfides at room temperature: Chem. Lett., 400 (2000).
  • {ALD} Merck:14,4037
  • {ALD} Merck:14,4037 Beilstein: 16,IV,1783
  • {ALF} Promotes the Pschorr cyclization of stilbene derivatives in acetone to give phenanthrenes: J. Org. Chem., 60, 196 (1995).
  • {PUB} PubChem --- A Bioorganometallic Approach for the Electrochemical Detection of Proteins: A Study on the Interaction of Ferrocene–Peptide Conjugates with Papain in Solution and on Au Surfaces --- https://pubmed.ncbi.nlm.nih.gov/17455185
  • {PUB} PubChem --- Calix[4]arenes Containing Ferrocene Amide as Carboxylate Anion Receptors and Sensors --- https://pubmed.ncbi.nlm.nih.gov/12713318
  • {PUB} PubChem --- Cytotoxicity of a series of ferrocene-containing beta-diketones --- https://pubmed.ncbi.nlm.nih.gov/19035310
  • {PUB} PubChem --- Disposable electrochemical immunosensor for carcinoembryonic antigen using ferrocene liposomes and MWCNT screen-printed electrode --- https://pubmed.ncbi.nlm.nih.gov/19038538
  • {PUB} PubChem --- Effect of the electrostatic microenvironment on the observed redox potential of electroactive supramolecular bioconjugates --- https://pubmed.ncbi.nlm.nih.gov/19030599
  • {PUB} PubChem --- Electrochemical Method for the Detection of Lipase Activity --- https://pubmed.ncbi.nlm.nih.gov/15828803
  • {PUB} PubChem --- Ferrocene Bound Poly(vinyl chloride) as Ion to Electron Transducer in Electrochemical Ion Sensors --- https://pubmed.ncbi.nlm.nih.gov/20666464
  • {PUB} PubChem --- Ferrocene Branched Chitosan for the Construction of a Reagentless Amperometric H
  • 102-54-5 H48204 Ferrocene
二茂铁

    化学属性

    Mol. FormulaC10H10Fe
    Mol. Weight186.03
    Density1.49
    Boiling Point249 °C at 760 mmHg
    Vapor Pressure0.03 mmHg ( 40 °C)
    Melting Point172-174 °C
    TSCAYes
    Solubility难溶
    Stability对空气,湿度和热敏感
    Flash Point100°C
    Appearance orange xtl.

    *以上化合物性质及应用等信息仅供参考