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Dimethyl (2-Oxopropyl)phosphonate 丙酮基膦酸二甲酯

规格: 95%
CAS: 4202-14-6
产品编号: H46956
MDL: MFCD00008769
品牌: INFI
Chemical NameDimethyl acetylmethylphosphonate
CAS Number4202-14-6
EC Number224-110-5
Beilstein Registry Number1766218
MDL NumberMFCD00008769
Synonym Dimethyl acetonylphosphonate
PubChem Substance ID77872
Chemical Name Translation丙酮基膦酸二甲酯
Reaxys-RN1766218
InChIKeyUOWIYNWMROWVDG-UHFFFAOYSA-N
LabNetwork Molecule IDLN00009226
InChIInChI=1S/C5H11O4P/c1-5(6)4-10(7,8-2)9-3/h4H2,1-3H3
Canonical SMILESCC(CP(OC)(OC)=O)=O
  • {ALD} Beilstein: 4,IV,3604
  • {ALF} Successive treatment with NaH and n-BuLi gives the dianion which can be alkylated or acylated on the terminal position: see. e.g.: Synth. Commun., 22, 219 (1992); J. Chem. Soc., Perkin 1, 2259 (1998).
  • {ALF} For use of ß-ketophosphonates in an annulation sequence for building a cyclohexadienone ring onto a cyclic ketone, see: Synthesis, 855 (1982):
  • {ALF} Horner-Wadsworth-Emmons precursor of ɑß-unsaturated ketones.
  • 4202-14-6 H46956 Dimethyl (2-Oxopropyl)phosphonate
丙酮基膦酸二甲酯

    化学属性

    Mol. FormulaC5H11O4P
    Mol. Weight166.11
    Density1.202
    Boiling Point227°C at 760 mmHg
    Refractive index1.4380 to 1.4410
    Flash Point93.4°C
    TSCANo

    *以上化合物性质及应用等信息仅供参考