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Zirconium(IV) tert-butoxide 叔丁醇锆

规格: 97%
CAS: 2081-12-1
产品编号: H45144
MDL: MFCD00075085
品牌: INFI
Chemical NameZirconium(IV) Tert-Butoxide
Synonym ZIRCONIUM T-BUTOXIDE 四叔丁醇锆 Zirconium (IV) tert-butoxide Zirconium tert-butanolate ZIRKONIUM(IV) TERT-BUTOXIDE ZIRKON(IV)-TERT-BUTOXID Zirconium(IV)t-butoxide(99.99%-Zr)PURATREM Zirconium(IV) tert-butoxide, 99% (metals basis) 四叔丁醇锆(IV), 99.99% (METALS BASIS) 叔丁醇锆 Tetra-tert-butyl zirconate Zirconium(IV) t-butoxide 四叔丁醇锆(IV), 99% (METALS BASIS) Tetra-tert-butoxyzirconium; Tetrakis(tert-butanolato)zirconium; Tetrakis(tert-butoxy)zirconium; Zirconium tert-butanolate; Zirconium tert-butoxide; Zirconium tetra-t-butoxide; Zirconium tetra-tert-butoxide; Zirconium tetrakis(tert-butoxide); Zirconium(4+) tert-butoxide; Zirconium(IV) tert-butanolate; Zirconium(IV) tert-butoxide; tert-Butanol zirconium(4+) salt Orthozirkonsäure-tert.-butylester Zirconium(IV) tert-butoxide, 97+% Zirconium(IV) tert-butoxide Tetra-tert-butoxyzirconium ZTB Zirconium tert-butanolate 四叔丁氧化锆 ZIRCONIUM TERT-BUTOXIDE ZIRCONIUM(IV) TERT-BUTOXIDE, 99.999% ZTB ZIRCONIUM(IV) TERT-BUTOXIDE ZIRCONIUM TETRA-T-BUTOXIDE 四叔丁醇锆(IV), 97+% 四叔丁氧化锆 Zirconium(IV)t-butoxide,99% Tetra-tert-butoxyzirconium TETRA-TERT-BUTYL ZIRCONATE ZIRCONIUM(IV)T-BUTOXIDE zirconium tetrakis-(tert-butoxide) Zirconium(IV) tert-butoxide, 99.95% ZIRCONIUM(IV) T-BUTOXIDE: 99.99% Zirkon(IV)-tert.-butylat 2-Propanol, 2-methyl-, zirconium(4+) salt Zirkon(IV)-tert.-butoxid Zirconium(IV) tert-butoxide, 99.99
PubChem Substance ID329766792
Beilstein Registry Number3681870
EC Number000-000-0
Chemical Name Translation四叔丁醇锆
LabNetwork Molecule IDLN02144733
MDL NumberMFCD00075085
CAS Number2081-12-1
GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
    Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
    Hazard Codes Xi
    Precautionary statements
    • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P305+P351+P338
      Signal word Warning
      Safety Statements
      • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
      • S37 Wear suitable gloves 戴适当手套；
      • S36 Wear suitable protective clothing 穿戴适当的防护服；
        Risk Statements
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
        • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
          Storage condition Moisture & Light Sensitive 2-8°C
          UN Number UN2924 1993
          Packing GroupIII
          Hazard Class3
          Restrict 危险品
        • {ALF} Catalyst for an improved version of the Oppenauer oxidation of primary and secondary alcohols to aldehydes and ketones (see Aluminum tert-butoxide, A16954, and Aluminum isopropoxide, 14007) which proceeds at room temperature in the presence of substoichiometric amounts of the catalyst, a moderate excess of chloral as the hydride acceptor and 3-an
        • {ALFA} Catalyst for an improved version of the Oppenauer oxidation of primary and secondary alcohols to aldehydes and ketones (see Aluminum tert-butoxide, A16954, and Aluminum isopropoxide, 14007) which proceeds at room temperature in the presence of substoichiometric amounts of the catalyst, a moderate excess of chloral as the hydride acceptor and 3-angstrom molecular sieves to prevent hydrolysis of the catalyst: Synthesis, 1341 (1996). In a related method, the reagent is used catalytically in the presence of t-butyl hydroperoxide or cumene hydroperoxide as the hydride acceptor under anhydrous conditions: J. Org. Chem., 61, 1467 (1996).
        • {uni_hamburg} Short: IV/18A
        • {uni_hamburg} Short: IV/20B
          • 2081-12-1 H45144 Zirconium(IV) tert-butoxide 叔丁醇锆

          化学属性

          Refractive indexn20/D 1.424(lit.)
          TSCANo
          Melting Point3°C
          Mol. FormulaC16H36O4Zr
          Mol. Weight384
          Density0.96
          Flash Point185°F
          Appearance slightly yellow liq.
          Stabilitymoisture sensitive, store cold
          Boiling Point90°C/5mm

          *以上化合物性质及应用等信息仅供参考

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