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Tris(dimethylamino)phosphine 三(二甲胺基)膦

规格: 99%

CAS: 1608-26-0

产品编号: H42476

MDL: MFCD00008301

品牌: INFI

Chemical Name	Hexamethylphosphorous Triamide
CAS Number	1608-26-0
Synonym	N,N,N',N',N'',N''-Hexamethylphosphinetriamine
MDL Number	MFCD00008301
EC Number	216-534-4
Beilstein Registry Number	4(4)274
PubChem Substance ID	87577088
Reaxys-RN	906778
Chemical Name Translation	三(二甲胺基)膦
LabNetwork Molecule ID	LN00226609
InChI	InChI=1S/C6H18N3P/c1-7(2)10(8(3)4)9(5)6/h1-6H3
Canonical SMILES	CN(C)P(N(C)C)N(C)C

Reagent combination with CCl4 for the conversion of hydroxyl groups to the corresponding chlorides; hydroxyl group activation; dehydrations.

{ALF} Has also been used for a variety of other reductions including that of ozonolysis intermediates: Helv. Chim. Acta, 50, 2387 (1967), and of primary alkyl nitro compounds to nitriles: Synthesis, 36 (1979). Bromohydrins can be converted to alkenes, by reductive elimination from their triflate esters: J. Am. Chem. Soc., 102, 1433 (1980):

{ALF} Reacts with BrCCl3 to give dichloromethylenephosphorane Cl2C=PPh3, which undergoes Wittig reaction with aldehydes to give 1,1-dichloroalkenes, giving better results than the CCl4/PPh3 combination: Tetrahedron Lett., 1237, 1239 (1977); Synthesis, 554 (1980). Similarly, with Br2CF2, the CF2 group can be transferred to both aldehydes and ketones: J. Fluorine Chem., 1, 123 (1971); Synth. Commun., 3, 197 (1973).

{ALF} Reduces aromatic aldehydes to symmetrical epoxides in good yield: J. Am. Chem. Soc., 85, 1884 (1963). Both cis- and trans-isomers are formed. For list of examples, see: Org. Synth. Coll., 5, 358 (1973). Under suitable conditions, reaction of the intermediate with a second aldehyde can lead to mixed deoxybenzoins or diaryl enamines: Synthesis, 225 (1991).

{TRC} Ryu, H., et al.: J. Mat. Sci., 41, 8265 (2006),

{uni_hamburg} Short: II/2

{uni_hamburg} Short: II/25D

1608-26-0 H42476 Tris(dimethylamino)phosphine
三(二甲胺基)膦

化学属性

Mol. Formula	C6H18N3P
Mol. Weight	163.21
Density	0.898
Refractive index	1.4640 to 1.4670
Boiling Point	160.3°C at 760 mmHg
Flash Point	27°C
TSCA	Yes
Melting Point	-44°C
Solubility	起反应
Stability	对空气敏感;热和湿度敏感
Appearance	yellow liq.

*以上化合物性质及应用等信息仅供参考

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催化剂

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有机硅

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Tris(dimethylamino)phosphine 三(二甲胺基)膦

规格: 99%

化学属性

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