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1-(Trimethylsilyl)propyne 1-(三甲基硅基)丙炔

规格: 98%
CAS: 6224-91-5
产品编号: H38919
MDL: MFCD00009271
品牌: INFI
Chemical Name1-(Trimethylsilyl)-1-propyne
CAS Number6224-91-5
Synonym Trimethyl(prop-1-yn-1-yl)silane
PubChem Substance ID87576914
EC Number228-314-5
Beilstein Registry Number1071311
MDL NumberMFCD00009271
Reaxys-RN1071311
Chemical Name Translation1-(三甲基硅基)丙炔
InChIKeyDCGLONGLPGISNX-UHFFFAOYSA-N
LabNetwork Molecule IDLN00194943
Canonical SMILESCC#C[Si](C)(C)C
IUPAC Nametrimethyl(prop-1-ynyl)silane
  • 经由钯催化的碳环合成高取代的茚类; 铑催化的和二溴苯硼酸的反应合成二氢茚酮(indenones);在Cp2Zr(H)CI存在下把醛转化成1,3-二烯烃等等。
  • {ALF} Alkylation of the lithio-derivative proceeds with only a small amount of allylic rearrangement to the allene, and is thus a useful route to substituted terminal alkynes: Tetrahedron Lett., 5041 (1968):
  • {SA} Beil. 4 ,IV,3938
  • {ALD} Beilstein: 4,IV,3938
  • {PUB} ChEMBL|Nature Chemical Biology|PubChem|Springer Nature --- Identification of the toxic trigger in mushroom poisoning --- https://pubmed.ncbi.nlm.nih.gov/19465932
  • {TRC} Falck, J., et al.: Bioorg. Med. Chem. Lett., 14, 4987 (2004),
  • {SA} J. Am. Chem. Soc. 129 , 5766, (2007) 摘要
  • {PUB} PubChem --- A Polymerized Calix[6]arene Monolayer Having Gas Permeation Selectivity that Exceeds Knudsen Diffusion --- https://pubmed.ncbi.nlm.nih.gov/12224927
  • {PUB} PubChem --- Probing the Intermediates of Halogen Addition to Alkynes: Bridged Halonium versus Open Halovinyl Cation; A Theoretical Study --- https://pubmed.ncbi.nlm.nih.gov/16268583
  • {PUB} PubChem --- Transition metal catalyzed manipulation of non-polar carbon–hydrogen bonds for synthetic purpose --- https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3165906
  • {PUB} PubChem|Springer Nature --- Controlling the sucrose concentration increases Coenzyme Q10 production in fed-batch culture of Agrobacterium tumefaciens\\n --- https://pubmed.ncbi.nlm.nih.gov/17479258
  • {PUB} PubChem|Springer Nature --- Recent developments on sustainable biobutanol production: a novel integrative review --- https://pubmed.ncbi.nlm.nih.gov/38981967
  • {uni_hamburg} Short: III/35F
  • {PUB} Springer Nature --- A Short Synthesis of Strychnine from Pyridine --- https://doi.org/10.1007/978-3-642-34065-9_4
  • {PUB} Springer Nature --- Application of Polymer Membranes to Alcohol Concentration in Fermentation of Biomass --- https://doi.org/10.1007/978-1-4899-0112-5_70
  • {PUB} Springer Nature --- Binuclear Iridium Complexes in Catalysis --- https://doi.org/10.1007/3418_2015_145
  • {PUB} Springer Nature --- Catalytic Addition of C – H Bonds to C – C\\n Multiple Bonds --- https://doi.org/10.1007/3418_2007_064
  • {PUB}
  • 6224-91-5 H38919 1-(Trimethylsilyl)propyne
1-(三甲基硅基)丙炔

    化学属性

    Mol. FormulaC6H12Si
    Mol. Weight112.24
    Refractive index1.4190 to 1.4210
    Boiling Point99-100°C at 760 mmHg
    Density0.758
    Flash Point-3.889°C
    TSCANo
    Melting Point-69°C
    Vapor Density>;1 (vs air)

    *以上化合物性质及应用等信息仅供参考