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Methyldiphenylphosphine oxide 甲基二苯基氧化膦

规格: 98%
CAS: 2129-89-7
产品编号: H29828
MDL: MFCD00002081
品牌: INFI
Chemical NameMethyldiphenylphosphine oxide
Synonym Methyldiphenylphosphine oxide
MDL NumberMFCD00002081
CAS Number2129-89-7
PubChem Substance ID75041
EC Number218-346-8
Beilstein Registry Number957291
Reaxys-RN957291
Chemical Name Translation甲基二苯基氧化膦
InChIKeyPEGCITODQASXKH-UHFFFAOYSA-N
InChIInChI=1S/C13H13OP/c1-15(14,12-8-4-2-5-9-12)13-10-6-3-7-11-13/h2-11H,1H3
LabNetwork Molecule IDLN00198535
Canonical SMILESCP(C1=CC=CC=C1)(C2=CC=CC=C2)=O
  • {uni_hamburg} Short: EINECS
  • {uni_hamburg} Short: III/35D2
  • {ALF} The lithiated derivative undergoes Horner olefination reactions with carbonyl compounds to give, after dehydration, vinyl or allyl phosphine oxides: Synthesis, 64 (1988). The reaction has been use in a useful synthesis of (3Z,6E)-ɑ-farnesene: J. Org. Chem., 60, 6211 (1995); for reaction scheme see Geranyl­ bromide, A14093. Epoxides give -hydroxy propylphosphine oxides: J. Chem. Soc., Perkin 1, 2971 (1988); see also: J. Chem. Soc., Perkin 1, 1963 (1999).
  • 2129-89-7 H29828 Methyldiphenylphosphine oxide
甲基二苯基氧化膦

    化学属性

    Mol. FormulaC13H13OP
    Mol. Weight216.22
    Melting Point111-115°C
    TSCANo
    Boiling Point180 °C at 1 mmHg
    Density1.0

    *以上化合物性质及应用等信息仅供参考