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Allylpalladium(II) chloride dimer 烯丙基氯化钯二聚物

规格: 98%

CAS: 12012-95-2

产品编号: H24051

MDL: MFCD00044874

品牌: INFI

Chemical Name	Allylpalladium(II) Chloride Dimer
Synonym	氯化烯丙基钯(II)二聚物 Bis(allyl)dichloropalladium Allyl palladium chloride dimer Diallyldichlorodipalladium 二(烯丙基)二氯二钯(II) Bis(allylchloropalladium) Bis(allyl)dichlorodipalladium 烯丙基氯化钯(II)二聚体，二(烯丙基)二氯二钯(II) 氯化烯丙基钯二聚物烯丙基氯化钯二聚物 ChemDose™ 片 [PdCl(C3H5)]2 Allylpalladium(II) chloride dimer Bis(allyl)dichlorodipalladium(II) Allylchloropalladium dimer Bis(allyl)dichlorodipalladium Bis(allyl)dichloropalladium Bis(allylchloropalladium) Diallyldichlorodipalladium [PdCl(C3H5)]2 [PdCl(allyl)]2 烯丙基氯化钯(II)二聚体 Allylchloropalladium dimer [PdCl(allyl)]2
EC Number	234-579-8
Beilstein Registry Number	4124623
PubChem Substance ID	61538
Chemical Name Translation	氯化烯丙基钯(II)二聚物
Wiswesser Line Notation	2U1-PD-G 2
InChIKey	TWKVUTXHANJYGH-UHFFFAOYSA-L
LabNetwork Molecule ID	LN00238817
InChI	InChI=1S/2C3H5.2ClH.2Pd/c21-3-2;;;;/h23H,1-2H2;21H;;/q2-1;;;2*+2/p-2
MDL Number	MFCD00044874
CAS Number	12012-95-2

GHS Symbol

RTECS	RT3510000
Safety Statements
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套； S36 Wear suitable protective clothing 穿戴适当的防护服； S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见； S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置； S37 Wear suitable gloves 戴适当手套；
Risk Statements
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition	Air & Moisture Sensitive 充氮密闭冷藏，置于阴凉干燥处。
WGK Germany	3
Precautionary statements
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。 P304+P340+P312 P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。 P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。 P305+P351+P338 P332+P313 P281 Use personal protective equipment as required. 使用所需的个人防护装备。 P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。 P301+P312+P330 P305+P351+P338+P337+P313
Hazard statements
H315 Causes skin irritation 会刺激皮肤 H319 Causes serious eye irritation 严重刺激眼睛 H335 May cause respiratory irritation 可能导致呼吸道刺激 H351 Suspected of causing cancer 怀疑致癌 H302+H312+H332
Signal word
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Hazard Codes	Xn Xi

1.烯烃对映选择性氢化硅烷化的预催化剂。

2.环丙烯基醋酸盐不对称烷化和氨化的预催化剂。

3.交叉耦联反应催化剂。

4.二聚体可以用作Trost配体。

5.作为高对映选择性烯丙基烷化和氨化的有用前体。

6.烯烃甲锡烷基化催化剂。

{ALF} Reacts with lithium enolates of esters, in the presence of CO and excess TMEDA, to give good yields of ɑ-cyclopropyl esters: Angew. Chem. Int. Ed., 31, 234 (1992).

{ALF} Used in combination with a chiral diamine to effect displacement of a mesylate with Trimethylsilyl azide, L00173, in the asymmetric synthesis of (+)-pancratistin: J. Am. Chem. Soc., 117, 10143 (1995).

12012-95-2 H24051 Allylpalladium(II) chloride dimer
烯丙基氯化钯二聚物

化学属性

Solubility	Very soluble in dichloromethane and dichloroethane. Slightly soluble in toluene, insoluble in water
TSCA	No
Density	6.68
Mol. Formula	C6H10Cl2Pd2
Stability	air sensitive, store cold
Appearance	yellow solid yellow xtl.
Mol. Weight	365.86
Melting Point	120°C dec.
pH	:A

*以上化合物性质及应用等信息仅供参考

电子化学品

催化剂

配体

有机硅

元素分类

其他精细新材料

Allylpalladium(II) chloride dimer 烯丙基氯化钯二聚物

规格: 98%

化学属性

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