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Gallium(III) chloride 氯化镓

规格: 99.99%
CAS: 13450-90-3
产品编号: H23780
MDL: MFCD00011018
品牌: INFI
Chemical NameGallium(III) Chloride
MDL NumberMFCD00011018
EC Number236-610-0
CAS Number13450-90-3
Merck Number4348
Synonym 三氯化镓 溶液 Gallium trichloride gallium trichloride Gallium(III) chloride Gallium chloride, GaCl3 Gallium(3+) chloride Gallium(III) chloride, anhydrous 三氯化镓 Gallium chloride (GaCl3) Gallium(III)-chlorid gallium (III) chloride Galliumchlorid (GaCl3) Trichlorogallium Gallium chloride
PubChem Substance ID87561610
Chemical Name Translation氯化镓(III)
Reaxys-RN3587236
Wiswesser Line NotationGA G3
LabNetwork Molecule IDLN01742455
GHS Symbol
TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 316 mg/m3/3H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 95,487,1949

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 43 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EQSSDX Environmental Quality and Safety, Supplement.  (Stuttgart, Fed. Rep.
   Ger.)  V.1-5, 1975-76. Discontinued.  Volume(issue)/page/year: 1,1,1975

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : 41 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EQSSDX Environmental Quality and Safety, Supplement.  (Stuttgart, Fed. Rep.
   Ger.)  V.1-5, 1975-76. Discontinued.  Volume(issue)/page/year: 1,1,1975

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 245 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EQSSDX Environmental Quality and Safety, Supplement.  (Stuttgart, Fed. Rep.
   Ger.)  V.1-5, 1975-76. Discontinued.  Volume(issue)/page/year: 1,1,1975

TYPE OF TEST            : LD50 - Le

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE

TYPE OF TEST            : DNA repair
TEST SYSTEM             : Bacteria - Bacillus subtilis
DOSE/DURATION           : 2350 ug/disc
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 264,163,1991

RTECSLW9100000
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
  • S30 Never add water to this product 切勿将水加入该产品中;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
  • S8 Keep container dry 保持容器干燥;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐:立即求医并出示该容器或标签;
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
    UN Number 3260 UN3260
    Risk Statements
    • R34 Causes burns 会导致灼伤
    • R14 Reacts violently with water 遇水会猛烈反应
    • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
    • R12 Extremely flammable 极端易燃
    • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
    • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
    • R51/53
      Storage condition Moisture Sensitive
      WGK Germany3
      Hazard Codes F+,C,N C C,N,F+
      Hazard statements
      • H290 May be corrosive to metals 可能腐蚀金属。
      • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
      • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
      • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
      • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
      • H224 Extremely flammable liquid and vapour 极端易燃液体和蒸气
        Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US)
        Precautionary statements
        • P303+P361+P353+P310+P363
        • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
        • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
        • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
        • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
        • P273 Avoid release to the environment. 避免释放到环境中。
        • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
        • P301+P310
        • P305+P351+P338
        • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
        • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
        • P501 Dispose of contents/container to..… 处理内容物/容器.....
        • P405 Store locked up. 上锁保管。
        • P304+P340
        • P303+P361+P353
        • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
        • P304+P340+P310
        • P301+P330+P331+P310
        • P234 Keep only in original container. 只保留在原来的容器中。
        • P305+P351+P338+P310
        • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
          Signal word Danger
          Packing GroupII
          Hazard Class8
        • {ALF} Lewis acid catalyst. For a brief feature as a reagent in synthesis, see: Synlett, 2440 (2003).
        • {uni_hamburg} Short: II/25A
        • {uni_hamburg} Short: III/20b
        • 13450-90-3 H23780 Gallium(III) chloride
氯化镓

          化学属性

          Mol. FormulaGaCl3
          Mol. Weight176
          Density0.688 g/mL at 25 °C
          Melting Point78 °C(lit.)
          SolubilityVery soluble in water. Soluble in benzene, carbon tetrachloride and carbon disulfide
          TSCAYes
          Boiling Point201°C(lit.)
          Vapor Pressure1 mmHg ( 48 °C)
          Flash Point-26 °F

          *以上化合物性质及应用等信息仅供参考