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Triphenylphosphine 三苯基膦

规格: 99.8%
CAS: 603-35-0
产品编号: H18421
MDL: MFCD00003043
品牌: INFI
Chemical NameTriphenylphosphine
MDL NumberMFCD00003043
CAS Number603-35-0
EC Number210-036-0
Beilstein Registry Number610776
Synonym Triphenylphosphine
Merck Number9743
PubChem Substance ID11776
Chemical Name Translation三苯基膦
Reaxys-RN610776
Wiswesser Line NotationRPR&R
LabNetwork Molecule IDLN00198869
InChIInChI=1S/C18H15P/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H
Canonical SMILESP(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3
  • 用于有机合成,聚合引发剂,抗菌素类药物氯洁霉素的原料,有机微量分析测定磷的标准样品。
  • {ALF} Azides can be converted selectively to amines, in the presence of ester, epoxide or nitro groups, by reduction to iminophosphoranes (Staudinger reaction), followed by hydrolysis. For reviews, see: Tetrahedron, 37, 437 (1981); 48, 1353 (1992):
  • {ALF} Finds widespread use as a complexing agent with transition metals, either in the preparation of stable complexes, or as an additive in metal-promoted reactions. See also Tri(o-tolyl)­phosphine, A12093 and Tri(2-furyl)­phosphine, L13329.
  • {ALF} For use in peptide and other coupling reactions, see 2,2'-Dipyridyl­ disulfide, A11118.
  • {ALF} In suitable circumstances, the iminophosphorane may undergo intramolecular aza-Wittig reaction: Tetrahedron, 45, 6375 (1989):
  • {ALF} Reviews: Aza-Wittig reaction in heterocyclic synthesis: Org. Prep. Proced. Int., 24, 209 (1992); Iminophosphoranes as building blocks for the preparation of N-containing heterocycles: Synthesis, 1197 (1994).
  • {ALD} Merck: 14,9743
  • Beilstein:16,759
  • {ALD} Merck: 14,9743
  • {ALF} For use in the Mitsunobu reaction for conversion of alcohols to alkylating agents, see N-Guanyl­urea sulfate, A19106, and Diisopropyl­ azodicarboxyl­ate, L10386. See also 1,2-Bis(diphenyl­phosphino)­ethane, A11419.
  • 603-35-0 H18421 Triphenylphosphine
三苯基膦

    化学属性

    Mol. FormulaC18H15P
    Mol. Weight262.29
    Density1.132
    Vapor Density9 (vs air)
    Boiling Point377
    Vapor Pressure5 mmHg ( 20 °C)
    Melting Point79-81
    Flash Point359°F
    TSCAYes
    SolubilitySoluble in ether, acetone, chloroform (50 mg/ml), and alcohol. Insoluble in water.
    Stability对光敏感
    Appearance white xtl.
    Danger-Level乙类
    pH-:-
    Redox-

    *以上化合物性质及应用等信息仅供参考