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Dimethylzinc 二甲基锌

规格: 1.0 M solution in hexanes, SpcSeal
CAS: 544-97-8
产品编号: H16153
MDL: MFCD00014854
品牌: INFI
Chemical NameDimethylzinc
Synonym (CH3)2Zn 2,4-二甲基锌 DIMETHYLZINC DIMETHYLZINC (10 WT% IN HEXANE) DIMETHYLZINC SOLUTION, ~1 M IN HEPTANE DIMETHYLZINC SOLUTION, ~2 M IN TOLUENE DIMETHYLZINC, 2.0M SOLUTION IN TOLUENE Dimethyl-zinc Dimethylzinc Dimethylzinc solution Dimethylzinc, 1.2M solution in toluene Dimethylzinc,GLCGrade Dimethylzinc,elec.gr.(99.999%-Zn)PURATREM Dimethylzinc,min.95%(10wt%inhexane)(Sure/Sealbottle) DimethylzincelecgrPURATREMcolorlessliq Dimethylzincmin Dimethylzincwtinhexane Zinc, dimethyl- dimethyl-zin dimethylzinc zincmethyl 二甲基鋅 二甲基锌 二甲基锌 溶液 二甲基锌, 95+% 二甲鋅 甲基锌
EC Number208-884-1
Beilstein Registry Number3587195
PubChem Substance ID11010
Merck Number14,3263
Chemical Name Translation二甲基锌
LabNetwork Molecule IDLN01313985
MDL NumberMFCD00014854
CAS Number544-97-8
InChIInChI=1S/2CH3.Zn/h2*1H3;/q2*-1;+2
GHS Symbol
Signal word
WGK Germany3
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐:立即求医并出示该容器或标签;
  • S46 If swallowed, seek medical advice immediately and show this container or label 食入时,立即求医并出示容器/标签;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
    Risk Statements
    • R11 Highly flammable 非常易燃
    • R48/20
    • R14 Reacts violently with water 遇水会猛烈反应
    • R34 Causes burns 会导致灼伤
    • R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
    • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
    • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
    • R51/53
    • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
    • R50/53
      Precautionary statements
      • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
      • P222 Do not allow contact with air. 不要与空气接触。
      • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能,因为会剧烈反应可能产生闪火。
      • P231 Handle under inert gas. 在惰性气体中操作。
      • P231+P232
      • P233 Keep container tightly closed. ?保持容器密闭。
      • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
      • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
      • P242 Use only non-sparking tools. 只能使用无火花工具。
      • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
      • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
      • P264+P265
      • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
      • P273 Avoid release to the environment. 避免释放到环境中。
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P301+P330+P331
      • P302+P334
      • P302+P335+P334
      • P302+P361+P354
      • P303+P361+P353
      • P304+P340
      • P305+P351+P338
      • P305+P354+P338
      • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
      • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
      • P316
      • P317
      • P319
      • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
      • P335+P334
      • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
      • P370+P378
      • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
      • P402+P404
      • P403+P233
      • P403+P235
      • P405 Store locked up. 上锁保管。
      • P422 Store contents under… 存储目录在…之下。
      • P501 Dispose of contents/container to..… 处理内容物/容器.....
        Hazard statements
        • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
        • H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
        • H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体,可自燃。
        • H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
        • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
        • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
        • H318 Causes serious eye damage 严重伤害眼睛
        • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
        • H361d Suspected of damaging the unborn child 怀疑对未出生婴儿造成伤害
        • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
        • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
        • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
          Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US) Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
          Packing GroupI
          UN Number 3399 UN3394
          Storage condition Air & Moisture Sensitive 0-6°C
          Hazard Codes F,C,N F,Xn,N
          Hazard Class4.2
          Warnings 危化品目录(2015)
          Restrict 危险品
        • {uni_hamburg} Short: II/25B
        • Title: Structure Data Of Free Polyatomic Molecules: Molecules containing One or Two Carbon Atoms
        • Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N.
        • Editor: Kuchitsu, K.
        • Source: Landolt-Börnstein, New Series
        • Volume: II/25B
        • Year: 1999
        • Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules
        • ISBN: 3-540-63645-5
        • ISBN: 978-3-540-63645-8
        • Internet Resource: DOI:10.1007/b68834
        • RefComment: IX, 512 pages. Hardcover
        • Abstract: Volume II/25 is a supplemented and revised edition of the preceding volumes II/7, II/15, II/21 and II/23 containing up to date information on inorganic and organic polyatomic molecules. All experimental methods for the determination of quantitative structural data of free molecules have been considered: microwave, infrared, Raman, electronic and photoelectron spectroscopy as well as electron diffraction. The data obtained by these methods have been critically evaluated and compiled. They are presented separately for each molecule, together with a schematic figure of the structure and the original literature.
        • {uni_hamburg} Short: III/35C4
        • Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Hydrogen-1, Part 4: Inorganic and Organometallic Compounds
        • Author: Gupta, R.R.; Platzer, N.
        • Editor: Gupta, R.R.; Lechner, M.D.
        • Source: Landolt-Börnstein, New Series
        • Volume: III/35C4
        • Year: 2001
        • Keyword: Hydrogen 1; Nuclear Magnetic Resonance
        • ISBN: 3-540-41059-7
        • ISBN: 978-3-540-41059-1
        • Internet Resource: DOI:10.1007/b76570
        • RefComment: VII, 299 pages. With CD-ROM. Hardcover
        • Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due
        • 544-97-8 H16153 Dimethylzinc
二甲基锌

          化学属性

          TSCAYes
          Solubility溶于醚,可混溶于石油醚、苯。
          Mol. FormulaC2H6Zn
          Mol. Weight95
          Density1.386 (20°C)
          Flash Point-1°F
          Appearance colorless liq.
          Stabilitymoisture sensitive
          Boiling Point46°C
          Melting Point-42°C
          pH:A

          *以上化合物性质及应用等信息仅供参考