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Azidotrimethylsilane 叠氮基三甲基硅烷

规格: 95%
CAS: 4648-54-8
产品编号: H11842
MDL: MFCD00001986
品牌: INFI
Chemical NameAzidotrimethylsilane
Synonym (CH3)3SiN3 1-(Trimethylsilyl)-1,3-diaza-2-azoniapropadiene-3-ide AZIDOTRIMETHYLSILANE Azidotrimethyl silane(97%) Azidotrimethylsilane Me3SiN3 Silane,azidotrimethyl- TMSA Trimethylazidosilane Trimethylsilazid Trimethylsilyl azide Trimethylsilylazide Trimethylsilylazide, typically 95% Trimethylsilylazide,95% Trimethylsilylazide,typically95% azido-trimethyl-silane azidotrimethylsilane trimethylsilyl azide zidotrimethylsilane 三甲基叠氮化硅 三甲基甲硅烷基叠氮的化合物 叠氮三甲基硅 叠氮三甲基硅烷 叠氮化三甲基硅烷 叠氮化三甲基硅烷; 三甲基甲硅烷基叠氮的化合物; 三甲基叠氮化硅;三甲基叠氮硅烷; 叠氮三甲基硅; 三甲基硅叠氮 叠氮基三甲基硅烷 叠氮基三甲基硅烷,三甲基叠氮硅烷 迭氮三甲基硅烷
CAS Number4648-54-8
PubChem Substance ID78378
EC Number225-078-5
Beilstein Registry Number1903730
MDL NumberMFCD00001986
Reaxys-RN1903730
Chemical Name Translation叠氮基三甲基硅烷
InChIKeySEDZOYHHAIAQIW-UHFFFAOYSA-N
LabNetwork Molecule IDLN00115863
InChIInChI=1S/C3H9N3Si/c1-7(2,3)6-5-4/h1-3H3
GHS Symbol
WGK Germany3
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H301 Toxic if swallowed 吞食有毒
  • H301+H311+H331
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H331 Toxic if inhaled 吸入中毒
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
    Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
    Hazard Codes 3 F,T F;T;N
    Precautionary statements
    • P201 Obtain special instructions before use. 使用前获取专门指示。
    • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
    • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
    • P233 Keep container tightly closed. ?保持容器密闭。
    • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
    • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
    • P241+P242+P243
    • P242 Use only non-sparking tools. 只能使用无火花工具。
    • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
    • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
    • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
    • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
    • P273 Avoid release to the environment. 避免释放到环境中。
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P301+P310
    • P301+P310+P330
    • P301+P316
    • P302+P352
    • P302+P352+P312+P361+P364
    • P303+P361+P353
    • P304+P340
    • P304+P340+P311
    • P308+P313
    • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
    • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
    • P316
    • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
    • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
    • P330 Rinse mouth. 漱口
    • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
    • P361+P364
    • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
    • P370+P378
    • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
    • P403+P233
    • P403+P235
    • P405 Store locked up. 上锁保管。
    • P501 Dispose of contents/container to..… 处理内容物/容器.....
      Signal word Danger
      UN Number 1992 UN 1992 3/PG 2
      Storage condition 0-10 0-10°C Moisture Sensitive Refrigerator 储存温度2-8°C 储存温度2-8°C; 充氩保存
      Risk Statements
      • R11 Highly flammable 非常易燃
      • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
      • R29 Contact with water liberates toxic gas. 遇水释放出有毒气体
      • R50/53
        Safety Statements
        • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
        • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
        • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
          Packing GroupII
          Hazard Class3/6.1
        • A versatile azidonation reagent
        • {ALF} In combination with triflic acid, is useful for the direct amination of aromatics. Aminodiazonium triflate is suggested as the active intermediate. Thus, benzene gives aniline in 95% yield and toluene gives a mixture of o- and p-toluidine: J. Org. Chem., 54, 1203 (1989). See also: Tetrahedron Lett., 32, 4321 (1991).
        • {ALF}
        • {ALF} Curtius reaction with acid halides gives isocyanates in one operation: Synth. Commun., 2, 227 (1972): Synthesis, 551 (1972); J. Org. Chem., 38, 2982 (1973). Similarly, pyridine-2,3-dicarboxylic anhydride is converted to 3-azaisatoic anhydride: Synthesis, 972 (1982):
        • {ALF} For reviews, see: Chem. Soc. Rev., 7, 15 (1978); Synthesis, 861 (1980); Chem. Rev., 88, 351 (1988).
        • {ALF} Mitsunobu reaction, in the presence of DIAD, with 1,2- and 1,3-diols leads to regioselective, stereospecific azidation to give predominantly the 2- or 3-azido alcohol with inversion of configuration: J. Org. Chem., 64, 6049 (1999).
        • {uni_hamburg} Short: II/25C
        • {ALF} Non-explosive hydrazoic acid equivalent in many cycloaddition reactions: e.g. with alkynes to give 1,2,3-triazoles: Chem. Ber., 99, 2512 (1966), nitriles, catalyzed by Di-n-butyl­tin oxide, L14491, to give tetrazoles: J. Org. Chem., 58, 4139 (1993).
        • {ALF} A mild, convenient synthesis of alkyl azides involves SN2 reaction with the corresponding alkyl halide, phosphate or tosylate, promoted by TBAF: Synthesis, 376 (1995).
        • {ALF} In combination withSnCl4,ß-D-ribofuranosyl acetates are converted to azides: Carbohydr. Res., 232, 359 (1992). Similarly, reaction with tert-halides in the presence of tin(IV) chloride gives tert-azides, which can be converted to iminophosphoranes by Staudinger reduction with Triethyl­ phosphite, L00339. Hydrolysis completes a one-pot sequence for the conversion of a tert-halide to the corresponding amine: Synthesis, 487 (1987).
          • 4648-54-8 H11842 Azidotrimethylsilane 叠氮基三甲基硅烷

          化学属性

          Mol. FormulaC3H9N3Si
          Mol. Weight115
          Refractive index1.4130 to 1.4170
          Boiling Point52-53
          Density0.868
          Flash Point6°C(lit.)
          TSCAYes
          Melting Point92-95°C
          SolubilitySoluble in water (decomposes), dichloromethane, ether, chloroform, and ethyl acetate.
          Appearance 无色液体。熔点-95℃，沸点95℃（96kPa），52-53℃（23.3kPa），相对密度0.87（20/4℃），折光率1.4140(20℃).
          Stability对湿度和热敏感

          *以上化合物性质及应用等信息仅供参考

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