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Ruthenium(III) chloride hydrate 三氯化钌(III)水合物

规格: 99%
CAS: 14898-67-0
产品编号: H11334
MDL: MFCD00149844
品牌: INFI
Chemical NameRuthenium(III) chloride
CAS Number14898-67-0
PubChem Substance ID24852386
EC Number233-167-5
MDL NumberMFCD00149844
Merck Number14,8302
Synonym Ruthenium(III) chloride hydrate, ReagentPlus®, 活性矾土 RUTHENIUM CHLORIDE HYDRATE ruthenium(iii) chloride hydrate, premion 氯化钌(III)水合物, PREMION|R, 99.99% (METALS BASIS) RUTHENIUM(III) CHLORIDE HYDRATE (35-40% RU) RUTHENIUM(III) CHLORIDE HYDRATE RutheniumchloridehydrateRu RUTHENIUM TRICHLORIDE N-HYDRATE 三氯化钌 三氯化钌水合物 氯化钌(III)水合物, 99.9% (PGM BASIS), RU 38% MIN Active oxidative aluminum Ruthenium trichloride 三氯化钌 水合物 RUTHENIUM(III)CHLORIDEHYDRATE,35-42%RU activated alumin(I)um oxide 三水氯化钌 RUTHENIUM(III) CHLORIDE RUTHENIUM TRICHLORIDE HYDRATE Ruthenium(III) chloride hydrate, 99.98% metals basis RUTHENIUM(+3)CHLORIDE HYDRATE 三氯化钌(III)水合物,;氯化钌(III)水合物 氯化釕 Ruthenium(III)-chlorid-hydrat RUTHENIUM(III) CHLORIDE N-HYDRATE RUTHENIUM CHLORIDE, HYDRATED REAGENT Ruthenium trichloride Trichlororuthenium hydrate 氯化钌(III)水合物 RUTHENIUM CHLORIDE, HYDROUS Ruthenium chloride (RuCl3), hydrate RUTHENIUM (III) CHLORIDE HYDRATE (40-43% RU) (99.9%-RU) 活性氧化铝
Beilstein Registry Number2384789
Chemical Name Translation一水合三氯化钌
CAS Number14898-67-0
LabNetwork Molecule IDLN00198876
GHS Symbol
WGK Germany3
Hazard Codes 8 C
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
    Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
    Precautionary statements
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P305+P351+P338
    • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
      Signal word Danger
      RTECSVM2650000
      Safety Statements
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
      • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服;
      • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
      • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
        Packing GroupII
        UN Number 3260 UN 3260 8/PG 2 UN3260
        Risk Statements
        • R34 Causes burns 会导致灼伤
          Storage condition 常温下密封干燥保存 Hygroscopic
          Hazard Class8
        • 1.多相催化或均相催化
        • 2.电镀、电解阳极
        • 与氧化剂发生氧化反应的催化剂
        • {ALF} In the presence of NaOH, is a catalyst for the high-yield rearrangement of sec-allylic alcohols to saturated ketones: J. Chem. Soc., Chem. Commun., 594 (1980). In MeOH, allyl alcohols are converted to allyl ethers. The thermodynamically more stable isomer predominates: Synth. Commun., 12, 807 (1982):
        • {ALF}
        • {SA} Merck 14 ,8302
        • {ALF} Used catalytically, in the presence of a suitable reoxidant, such as periodate or sometimes hypochlorite, RuCl3 is a source of the powerful oxidizing agent, ruthenium(VIII) oxide, RuO4: J. Org. Chem., 46, 3936 (1981); J. Am. Chem. Soc., 103, 464 (1981).
        • {ALF} Oxidations by RuO4 include: Alkenes to carboxylic acids: J. Am. Chem. Soc., 103, 464 (1981); Org. Synth. Coll., 8, 377 (1993). In biphasic solvent systems, the reaction can also be controlled to give good yields of syn-diols: Angew. Chem. Int. Ed., 33, 2312 (1994); Chem. Eur. J., 2, 50 (1996). For an improved protocol, employing only 0.5 mol% catalyst, see: Org. Lett., 5, 3353 (2003). For oxidation of diols to carboxylic acids: J. Org. Chem., 53, 5185 (1988). `,a-Enones to carboxylic acids: J. Org. Chem., 52, 689 (1987). Alkynes to `-diketones: Helv. Chim. Acta, 71, 237 (1988). Ethers to esters: Tetrahedron Lett., 24, 3829 (1983). Amines to amides: Chem. Pharm. Bull., 36, 3125 (1988). Methylbenzenes to benzoic acids: J. Org. Chem., 51, 2880 (1986). For the oxidation of alkenes, al
        • {ALF} For a brief survey of uses of RuC3 in Organic synthesis, see: Synlett, 1974 (2007).
        • {ALF} In the presence of 2,2'-bipyridine, catalyzes the stereospecific epoxidation of alkenes. The configuration of the alkene is retained: Tetrahedron Lett., 25, 3187 (1984).
        • {ALF} Oxidations by RuO4 include: Alkenes to carboxylic acids: J. Am. Chem. Soc., 103, 464 (1981); Org. Synth. Coll., 8, 377 (1993). In biphasic solvent systems, the reaction can also be controlled to give good yields of syn-diols: Angew. Chem. Int. Ed., 33, 2312 (1994); Chem. Eur. J., 2, 50 (1996). For an improved protocol, emplo
        • 14898-67-0 H11334 Ruthenium(III) chloride hydrate
三氯化钌(III)水合物

          化学属性

          Mol. FormulaRuCl3· xH2O
          Mol. Weight207.43 (anhydrous basis)
          Melting Point>300
          SolubilityVery soluble in water. Soluble in alcohol, acetone
          TSCAYes
          Density1.422
          Stability易吸潮
          Mol. FormulaRuCl3
          Appearance black pwdr.
          Mol. Weight207
          Stabilityhygroscopic