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Ruthenium(III) chloride hydrate 三氯化钌(III)水合物

规格: 99%

CAS: 14898-67-0

产品编号: H11334

MDL: MFCD00149844

品牌: INFI

Chemical Name	Ruthenium(III)Chloride Hydrate
CAS Number	14898-67-0
PubChem Substance ID	24852386
EC Number	233-167-5
MDL Number	MFCD00149844
Merck Number	14,8302
Synonym	Ruthenium(III) chloride hydrate, ReagentPlus®, 活性矾土 RUTHENIUM CHLORIDE HYDRATE ruthenium(iii) chloride hydrate, premion 氯化钌(III)水合物, PREMION\|R, 99.99% (METALS BASIS) RUTHENIUM(III) CHLORIDE HYDRATE (35-40% RU) RUTHENIUM(III) CHLORIDE HYDRATE RutheniumchloridehydrateRu RUTHENIUM TRICHLORIDE N-HYDRATE 三氯化钌三氯化钌水合物氯化钌(III)水合物, 99.9% (PGM BASIS), RU 38% MIN Active oxidative aluminum Ruthenium trichloride 三氯化钌水合物 RUTHENIUM(III)CHLORIDEHYDRATE,35-42%RU activated alumin(I)um oxide 三水氯化钌 RUTHENIUM(III) CHLORIDE RUTHENIUM TRICHLORIDE HYDRATE Ruthenium(III) chloride hydrate, 99.98% metals basis RUTHENIUM(+3)CHLORIDE HYDRATE 三氯化钌(III)水合物,;氯化钌(III)水合物氯化釕 Ruthenium(III)-chlorid-hydrat RUTHENIUM(III) CHLORIDE N-HYDRATE RUTHENIUM CHLORIDE, HYDRATED REAGENT Ruthenium trichloride Trichlororuthenium hydrate 氯化钌(III)水合物 RUTHENIUM CHLORIDE, HYDROUS Ruthenium chloride (RuCl3), hydrate RUTHENIUM (III) CHLORIDE HYDRATE (40-43% RU) (99.9%-RU) 活性氧化铝
Beilstein Registry Number	2384789
Chemical Name Translation	三氯化钌水合物
LabNetwork Molecule ID	LN00198876

1.多相催化或均相催化

2.电镀、电解阳极

与氧化剂发生氧化反应的催化剂

{ALF} In the presence of NaOH, is a catalyst for the high-yield rearrangement of sec-allylic alcohols to saturated ketones: J. Chem. Soc., Chem. Commun., 594 (1980). In MeOH, allyl alcohols are converted to allyl ethers. The thermodynamically more stable isomer predominates: Synth. Commun., 12, 807 (1982):

{ALF}

{SA} Merck 14 ,8302

{ALF} Used catalytically, in the presence of a suitable reoxidant, such as periodate or sometimes hypochlorite, RuCl3 is a source of the powerful oxidizing agent, ruthenium(VIII) oxide, RuO4: J. Org. Chem., 46, 3936 (1981); J. Am. Chem. Soc., 103, 464 (1981).

{ALF} Oxidations by RuO4 include: Alkenes to carboxylic acids: J. Am. Chem. Soc., 103, 464 (1981); Org. Synth. Coll., 8, 377 (1993). In biphasic solvent systems, the reaction can also be controlled to give good yields of syn-diols: Angew. Chem. Int. Ed., 33, 2312 (1994); Chem. Eur. J., 2, 50 (1996). For an improved protocol, employing only 0.5 mol% catalyst, see: Org. Lett., 5, 3353 (2003). For oxidation of diols to carboxylic acids: J. Org. Chem., 53, 5185 (1988). `,a-Enones to carboxylic acids: J. Org. Chem., 52, 689 (1987). Alkynes to `-diketones: Helv. Chim. Acta, 71, 237 (1988). Ethers to esters: Tetrahedron Lett., 24, 3829 (1983). Amines to amides: Chem. Pharm. Bull., 36, 3125 (1988). Methylbenzenes to benzoic acids: J. Org. Chem., 51, 2880 (1986). For the oxidation of alkenes, al

{ALF} For a brief survey of uses of RuC3 in Organic synthesis, see: Synlett, 1974 (2007).

{ALF} In the presence of 2,2'-bipyridine, catalyzes the stereospecific epoxidation of alkenes. The configuration of the alkene is retained: Tetrahedron Lett., 25, 3187 (1984).

14898-67-0 H11334 Ruthenium(III) chloride hydrate
三氯化钌(III)水合物

化学属性

Mol. Formula	RuCl3
Mol. Weight	207
Melting Point	> 300 °C
Solubility	Very soluble in water. Soluble in alcohol, acetone
TSCA	Yes
Density	1.422
Stability	易吸潮
Appearance	black pwdr.

*以上化合物性质及应用等信息仅供参考

电子化学品

催化剂

配体

有机硅

元素分类

其他精细新材料

Ruthenium(III) chloride hydrate 三氯化钌(III)水合物

规格: 99%

化学属性

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